Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
580983 | Journal of Hazardous Materials | 2010 | 5 Pages |
Abstract
A novel carbon paste ion selective electrode for determination of trace amount of lead was prepared. Multi-walled carbon nanotubes (MWCNTs) and nanosilica were used for improvement of a lead carbon paste sensor response. MWCNTs have a good conductivity which helps the transduction of the signal in carbon paste electrode. The electrode composition of 20 wt% paraffin oil, 57% graphite powder, 15% ionophore (thiram), 5% MWCNTs, and 3% nanosilica showed the stable potential response to Pb2+ ions with the Nernstian slope of 29.8 (±0.2) mV decadeâ1 over a wide linear concentration range of 10â7-10â2 mol Lâ1. The electrode has fast response time, and long term stability (more than 2 months). The proposed electrode was used to determine the concentration of lead ions in waste water and black tea samples.
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Authors
Mohammad Reza Ganjali, Negar Motakef-Kazami, Farnoush Faridbod, Sepideh Khoee, Parviz Norouzi,