Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
58156 | Catalysis Today | 2007 | 5 Pages |
Abstract
The interaction of nitric oxide with Ce0.75Zr0.25O2 solid solution were investigated by means of EPR and IR spectroscopies. The influence of adsorption parameters such as adsorption temperature and pressure, presence of the O2 co-reactant on the nature and relative surface abundance of the resultant mono- and dimeric NO species was elucidated. The thermal stability of the surface nitrosyl complexes and their reactivity toward dioxygen were also examined.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Andrzej Adamski, Gérald Djéga-Mariadassou, Zbigniew Sojka,