| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 58176 | Catalysis Today | 2007 | 4 Pages |
Abstract
Transient isotopic studies in the temporal analysis of products (TAP) reactor evidenced the importance of the lifetime of oxygen species generated upon N2O decomposition on extraframework iron sites of Fe-silicalite for methane oxidation at 723 K. Fe-silicalite effectively activates CH4 when N2O and CH4 are pulsed together in the reactor. However, these oxygen species gradually become inactive for methane oxidation as the time delay between the N2O and CH4 pulses is increased from 0 to 2 s.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Evgenii V. Kondratenko, Javier Pérez-Ramírez,