Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
581799 | Journal of Hazardous Materials | 2009 | 7 Pages |
Abstract
The leaching behaviour of fly ash (FA) from a secondary Pb smelter was assessed using the pH-static leaching experiment according to prEN 14997 (pH range 3-11) coupled with mineralogical investigation of the leached FA by XRD and Rietveld analyses and thermodynamic modelling using PHREEQC-2. The procedure was performed on fresh FA and FA washed at a cumulative L/S ratio of 60Â l/kg to remove readily soluble salts. For both fresh and washed FA, high amounts of inorganic contaminants were released under acidic conditions, exhibiting L-shaped leaching patterns: up to 300Â g Pb/kg, 4.5Â g Cd/kg, 4Â g Zn/kg, 1.05Â g As/kg and 70Â mg Sb/kg. The washing of soluble salts significantly decreased the leachability of Cd, Zn, As and Sb and increased the release of Pb, especially under acidic conditions. The leaching of fresh FA removed part of primary caracolite and all the KPb2Cl5 and NaCl. The Pb release was controlled by the precipitation of anglesite and PbSO3 under acidic conditions and of laurionite and carbonates (hydrocerussite and phosgenite) under alkaline conditions. In contrast, the washed FA was composed mainly of anglesite and PbSO3, both phases being the main solubility-controlling phases for Pb over the whole studied pH range.
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Authors
Martina VÃtková, VojtÄch Ettler, OndÅej Å ebek, Martin MihaljeviÄ, TomáÅ¡ Grygar, Jan Rohovec,