Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
581856 | Journal of Hazardous Materials | 2009 | 8 Pages |
Abstract
The adsorption of Ni(II) on oxidized multi-walled carbon nanotubes (MWCNTs) as a function of contact time, pH and foreign ions in the absence and presence of polyacrylic acid (PAA) was studied using batch technique. The results indicated that adsorption of Ni(II) on oxidized MWCNTs increased from zero to â¼99% at pH 2-9, and then maintained the high level with increasing pH. Kinetic data showed that the adsorption process achieved equilibrium within 2Â h and experimental data were fitted well by the pseudo-second-order equation. A positive effect of PAA on Ni(II) adsorption was found at pHÂ <Â 8, whereas a negative effect was observed at pHÂ >Â 8. The effect of addition sequences of PAA/Ni(II) on the adsorption of Ni(II) to PAA-MWCNT hybrids were also studied. The results indicated that the adsorption of Ni(II) was influenced by addition sequences obviously. The adsorption of Ni(II) on oxidized MWCNTs may be mainly attributed to surface complexation and ion exchange. Oxidized MWCNTs are suitable material in the solidification and pre-concentration of Ni(II) from aqueous solutions.
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Physical Sciences and Engineering
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Authors
Shitong Yang, Jiaxing Li, Dadong Shao, Jun Hu, Xiangke Wang,