Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
582156 | Journal of Hazardous Materials | 2009 | 7 Pages |
Abstract
Surface soil (0-5 cm) from various agricultural sites in Delhi was analyzed to discern the contents of 16 priority polycyclic aromatic hydrocarbons (PAHs). Reference and deuterated standards were used for identification and quantification of PAHs by high performance liquid chromatography (HPLC) with UV detection. â16PAHs ranged from 830 to 3880 μg kgâ1 (dry wt.) with an arithmetic mean of 1910 ± 1020 μg kgâ1 â16PAHs values at the urban sites were 2-5 times higher as compared to the rural sites. In general, low molecular weight PAHs were predominant. Total organic carbon (TOC) was found to be significantly correlated with â16PAHs. Isomer pair ratios and Principal component analysis (PCA) suggested biomass and fossil fuel combustion as the main sources of PAHs. The toxic equivalency factors (TEFs) were used to estimate benzo[a]pyrene-equivalent concentration (B[a]Peq). Therewith, PAH content of urban agricultural soil was found to have more carcinogenic potential.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Tripti Agarwal, P.S. Khillare, Vijay Shridhar, Sharmila Ray,