Article ID Journal Published Year Pages File Type
582346 Journal of Hazardous Materials 2009 6 Pages PDF
Abstract
A series of composite solid superacid catalysts SO42−/ZrO2-MxOy (M = Ti, Ni, Si) were prepared and investigated by means of Fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS). All catalysts exhibit good catalytic activity in the electrochemical reaction of p-xylene with methanol assisted with a pair of porous graphite plane electrodes and the selectivity of main products higher than 90% were observed. In particular, SO42−/ZrO2-SiO2 catalyst exhibited excellent catalytic activity. According to the experimental results, a possible free radical reaction mechanism confirmed by XPS and ultraviolet-visible (UV-vis) spectra was proposed. It may be concluded that a simple and feasible electrochemical catalytic oxidation reaction at room temperature and standard atmosphere may be possible.
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Health and Safety
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