Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
582784 | Journal of Hazardous Materials | 2008 | 6 Pages |
Abstract
An energetic coordination compound [Cd(DAT)6](ClO4)2 has been synthesized by using 1,5-diaminotetrazole (DAT) as ligand and its structure has been characterized by applying X-ray single crystal diffraction, elemental analysis and FT-IR spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and distorted octahedral structure. Di-dimension layer structure was formed and the layers were linked together by the extensive intermolecular hydrogen bonds between DAT ligands and ClO4â anions. Thermal decomposition mechanism of the title compound was predicted based on DSC, TG-DTG and FT-IR analyses results. The kinetic parameters of the first exothermic process of the title compound were studied by applying the Kissinger's and Ozawa-Doyle's methods. Sensitivity tests reveal that the title compound has sensitive nature.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Yan Cui, Jianguo Zhang, Tonglai Zhang, Li Yang, Jin Zhang, Xiaochun Hu,