Characterization of the fine fraction of the argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry

The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry is a hazardous waste due to the presence of chromium. While its coarse fraction is usually recycled into the own industrial process, the fine fraction is normally disposed in landfills. Techniques such as briquetting or magnetic separation were found to be inadequate to treat it for reuse purposes. So, in this work, the fine fraction of the AOD-L sludge was characterized aiming to find alternative methods to treat it. This sludge consists of a fine powder (mean diameter of 1 μm) containing 34 ± 2% (w/w) of iron, 10.2 ± 0.9% (w/w) of chromium and 1.4 ± 0.1% (w/w) of nickel. The main crystalline phases identified in this study were chromite (FeCr2O4), magnetite (Fe3O4), hematite (Fe2O3) and calcite (CaCO3). In the digestion tests, the addition of HClO4 has favored the dissolution of chromite which is a very stable oxide in aqueous media. Nickel was found in very fine particles, probably in the metallic form or associated with iron and oxygen. The sludge was classified as hazardous waste, so its disposal in landfills should be avoided.