In vitro release dynamics of thiram fungicide from starch and poly(methacrylic acid)-based hydrogels

In order to make the judicious use of pesticide/fungicide and to maintain the environment and ecosystem we have developed the starch and poly(methacrylic acid)-based agrochemical delivery system for their controlled and sustained release. The delivery device was prepared by using N,N′-methylenebisacrylamide (N,N′-MBAAm) as crosslinker and was characterized with FTIR, TGA and with swelling studies as a function of time and crosslinker concentration. This article discusses the swelling kinetics of polymer matrix and release dynamics of thiram (fungicide) from hydrogels for the evaluation of the diffusion mechanism and diffusion coefficients. The values of the diffusion exponent 'n' for both cases, that is the swelling of hydrogels and for the release of thiram from the hydrogels have been observed between 0.7 and 0.9 when the concentration of the crosslinker in the polymers were varied from 6.49 × 10−3 to 32.43 × 10−3 moles/L. It is inferred from the values of the 'n' that Non-Fickian diffusion mechanism has occurred in both the cases.