Article ID Journal Published Year Pages File Type
584900 Journal of Hazardous Materials 2007 5 Pages PDF
Abstract
The photooxidative degradation of 4-nitrophenol (4-NP) was studied in the UV/H2O2 process. The effects of applied H2O2 dose, initial 4-NP concentration and UV light intensity have been studied. Degradation was complete in 13 min and follows apparent first-order kinetics. The removal efficiency of 4-NP depends on the operational parameters and increases as the initial concentration of H2O2 and light intensity are increased but it decreases when the initial concentration of 4-NP is increased. From HPLC analysis, major intermediate products were hydroxyl derivatives of 4-NP as a result of photooxidative hydroxylation.
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Physical Sciences and Engineering Chemical Engineering Chemical Health and Safety
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