Levels of polychlorinated biphenyls (PCBs) in transformer oils from Korea

Using Korean waste official method, polychlorinated biphenyls (PCBs) were analyzed from 33 transformer oils collected under National Institute of Environmental Research (NIER) in Republic of Korea (ROK) and their emission rate in Korea was estimated. Practical quantification limits analyzed by this method were in the ranges of 0.02 and 0.05 mg L−1, and recovery of samples was in the ranges of 77-97%. The analytical results showed that PCBs in the transformer oils were identified as Aroclor 1242, 1254 or 1260. Twenty-nine samples were determined to contain PCBs of >0.05 mg L−1 and among these samples, nine samples contained to have >2 mg kg−1 which is limit of Waste Control Act (WCA) with regard to PCBs in transformer oil from Korea. The concentrations of PCBs in transformer oils were between N.D. (not detected) and 48.33 mg kg−1. PCBs concentrations did not exceed 50 mg kg−1 which is generally accepted limit for the definition of waste in POPs Guideline of Basel Convention.