Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
585224 | Journal of Hazardous Materials | 2006 | 6 Pages |
Abstract
Chlorinated phenolic compounds present in some chemical industry wastewaters cause severe toxic effects on the organisms and often are resistant to biological degradation. Synthetic wastewater containing different concentrations of para-chlorophenol (4-chlorophenol, 4-CP) was biologically treated in an activated sludge unit for COD, 4-CP and toxicity removal. Effects of feed 4-CP concentration on COD, 4-CP, toxicity removals and on sludge volume index were investigated at a constant sludge age of 20 days and hydraulic residence time (HRT) of 25 h. Resazurin method based on dehydrogenase activity was used for determination of the toxicity of the feed and effluent wastewater. COD and 4-CP removals were not affected by the presence of 4-CP in the wastewater up to feed 4-CP concentration of 925 mg lâ1 because of almost complete degradation of 4-CP yielding lower than 50 mg lâ1 4-CP in the aeration tank. Percent COD, 4-CP and toxicity removals decreased and the effluent COD, 4-CP and toxicity levels increased with further increases in the feed 4-CP concentrations above 925 mg lâ1 because of inhibitory concentrations of 4-CP in the reactor. Biomass concentration in the aeration tank decreased and the sludge volume index (SVI) increased with feed 4-CP concentrations above 925 mg lâ1 resulting in lower COD and 4-CP removal rates. The rates of COD and 4-CP removals indicated substrate (4-CP) inhibition for the feed 4-CP concentrations above 925 mg lâ1 corresponding to the reactor 4-CP of above 200 mg lâ1. The system should be operated at the feed 4-CP concentrations of less than 900 mg lâ1 (4-CPR < 200 mg lâ1) in order to obtain high rates and extents of COD, 4-CP and toxicity removals at a sludge age of 20 days and HRT of 25 h.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Fikret Kargi, Isil Konya,