Article ID Journal Published Year Pages File Type
588069 Process Safety and Environmental Protection 2016 10 Pages PDF
Abstract

•RuO2 catalyst was active for the gasification of plastics in supercritical water.•CGE of up to 99 wt% and HGE of over 100 wt% were achieved with 20 wt% RuO2.•Methane, hydrogen and carbon dioxide were the major gas products.•Detailed catalytic reaction mechanisms have been proposed for SCWG of plastics.•Catalytic process led to hydrocarbons clean-up in water and fuel gas production.

Here we report on a potential catalytic process for efficient clean-up of plastic pollution in waters, such as the Great Pacific Garbage Patch (GPGP). Detailed catalytic mechanisms of RuO2 during supercritical water gasification of common polyolefin plastics including low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (PP) and polystyrene (PP) have been investigated in a batch reactor at 450 °C for 60 min. All four plastics gave very high carbon gasification efficiencies (CGE) and hydrogen gasification efficiencies (HGE). Methane was the highest gas component, with a yield of up to 37 mol kg−1 LDPE using the 20 wt% RuO2 catalyst. Evaluation of the gas yields, CGE and HGE revealed that the conversion of PS involved thermal degradation, steam reforming and methanation; whereas hydrogenolysis was a possible additional mechanism during the conversion of aliphatic plastics. The process has the benefits of producing a clean-pressurized methane-rich fuel gas as well as cleaning up hydrocarbons-polluted waters.

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Physical Sciences and Engineering Chemical Engineering Chemical Health and Safety
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