High surface area Mo–V–Te–Nb–O catalysts: Preparation, characterization and catalytic behaviour in ammoxidation of propane

Mo–V–Te–Nb mixed oxides with a molar ratio of 1:0.30:0.20:0.15 were prepared by citrate and dry-up method, both associated with hydrothermal treatments in the presence of a cationic surfactant (cetyl trimethylammonium bromide, CTAB), and tested in the ammoxidation of propane. The catalysts were characterized by adsorption–desorption isotherms of nitrogen at 77 K, particle size measurements, XRD, and XPS. By using the surfactant, the surface area increased significantly, and samples with surface area between 110 and 239 m2/g were obtained. These catalysts exhibited a propane conversion near 48% with selectivity to acrylonitrile of about 32% for a space velocity 30 times higher than generally reported.