Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
58849 | Catalysis Today | 2006 | 11 Pages |
Abstract
Reacting triethyl aluminum and diethyl aluminum chloride with the chelating bisphenol ligands mdtbpH2 and mmcpH2 [mmcpH2: 2,2′-methylenebis(4-methyl-6-(1-methyl-cyclohexyl)phenol); mdtbpH2: 2,2′-methylenebis(4,6-di-tert-butyl-phenol)] afforded monomeric and dimeric aluminum bisphenoxides with reactive Al–Cl and Al–C2H5 moieties. We present here the X-ray structure determination of some of the isolated compounds as well as the preliminary catalytic tests in copolymerization reactions with cyclohexene oxide and carbon dioxide.
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Thomas A. Zevaco, Jakub Sypien, Annette Janssen, Olaf Walter, Eckhard Dinjus,