Article ID Journal Published Year Pages File Type
59026 Chinese Journal of Catalysis 2013 7 Pages PDF
Abstract

A column padding silica gel was used to support 2,2,6,6-tetramethylpiperdine-1-oxyl (TEMPO) and to adsorb NOx to provide an oxidant system for the selective oxidation of alcohols. A wide range of alcohols were oxidized to the corresponding aldehydes and ketones with high selectivities and conversions using this heterogeneous catalyst under mild conditions.

Graphical AbstractThe gas-solid one body catalyst, silica gel-TEMPO-NOx, was prepared by immbolizing TEMPO on silica gel and then absorbing NOx. Silica gel-TEMPO-NOx expressed good performance in the selective oxidation of alcohols under mild conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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