IEP as a parameter characterizing the pH-dependent surface charging of materials other than metal oxides

The numerical values of points of zero charge (PZC, obtained by potentiometric titration) and of isoelectric points (IEP) of various materials reported in the literature have been analyzed. In sets of results reported for the same chemical compound (corresponding to certain chemical formula and crystallographic structure), the IEP are relatively consistent. In contrast, in materials other than metal oxides, the sets of PZC are inconsistent. In view of the inconsistence in the sets of PZC and of the discrepancies between PZC and IEP reported for the same material, it seems that IEP is more suitable than PZC as the unique number characterizing the pH-dependent surface charging of materials other than metal oxides. The present approach is opposite to the usual approach, in which the PZC and IEP are considered as two equally important parameters characterizing the pH-dependent surface charging of materials other than metal oxides.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Well-organized, up-to-date and critical summary of IEP of various materials. ► Erroneous results have been filtered out. ► Complements a previous review in Advances CIS devoted to metal oxides.