Article ID Journal Published Year Pages File Type
591417 Colloid and Interface Science Communications 2014 4 Pages PDF
Abstract

•Authors report applications of X-ray micro computed tomography (microCT) to reveal the 3D multiphase interface and contact line.•A method is proposed to evaluate the volume and surface within the apparent external contact line.•Wetting behavior on anisotropic surfaces, where no simplified model can be applied due to the topological complexity, is investigated.•Natural (leaves) and artificial (gas diffusion layers) superhydrophobic surfaces are used as examples.

The investigation of multiphase interfaces and contact lines is a challenging research topic for comprehension of countless physical problems, both natural and imitated from nature, at the microscale (nearly 1 μm).In presence of a three-phase interaction (liquid–gas–solid, or two immiscible liquids and a solid), different forces influence the evolution of the system and lead it towards its mechanical equilibrium. Even for the seemingly very simple case of drops on solid surfaces, there are many attempts to investigate the involved effects, with the main aim to profitably replicate them for functional applications (biomimetics).Here we show that it is possible to visualize the real multiphase interface by X-ray micro-computed tomography (microCT), which is essentially a full volume 3D microscope, non-intrusive, with micrometric spatial resolution and suitable to operate even with matter opaque at visible wavelength.Consequently, microCT can also be applied to investigate complex wetting scenarios, to validate the theoretical models already available for such cases.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Colloid and Surface Chemistry
Authors
, ,