Bifunctional palladium composite membrane for hydrogen separation and catalytic CO methanation

NiO was introduced into the porous Al2O3 substrate by impregnation, and the resulting NiO/Al2O3 was coated with the lead of a 2B pencil to modify its surface. A palladium layer with a thickness of 5 μm was deposited by electroless plating on the Pencil/NiO/Al2O3 substrate, and a Pd/Pencil/Ni/Al2O3 membrane was obtained after reduction with hydrogen. For reference, a Ni-free Pd/Pencil/Al2O3 membrane was also fabricated. The surface and cross-sectional morphologies of the membranes were studied by scanning electron microscopy and metallographic microscopy. The hydrogen permeation kinetics was investigated by single gas tests, and the hydrogen separation performances of the Pd/Pencil/Al2O3 and Pd/Pencil/NiO/Al2O3 membranes were tested with a hydrogen feed composed of H2 77.8%, CO 5.2%, CO2 13.5%, and CH4 3.5%. The Ni-free Pd/Pencil/Al2O3 membrane only shows function of hydrogen separation, while the Pd/Pencil/Ni/Al2O3 is also catalytically effective for methanation of CO and CO2 in hydrogen, forming a bifunctional palladium membrane concept. Since the amount of CO and CO2 in the hydrogen after membrane separation is very low, the consumption of hydrogen by the methanation reactions is negligible. The bifunctional membrane is promising for proton exchange membrane fuel cells because the catalytic methanation treatment solves the CO poisoning problem of the fuel cell electrodes and consequently allows the palladium membrane to tolerate more membrane defects and to achieve longer life.

Graphical AbstractAiming at the hydrogen purification for proton exchange membrane fuel cells, a bifunctional Pd/Pencil/Ni/Al2O3 membrane that is capable of hydrogen separation and catalytic CO methanation was developed. It was compared with the Pd/Pencil/Al2O3 membrane without the nickel methanation catalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide