Article ID Journal Published Year Pages File Type
59240 Chinese Journal of Catalysis 2012 10 Pages PDF
Abstract

A chromatographic method and a dynamic Wicke-Kallenbach method (DMWK) were used to determine the diffusion characteristics of two industrial copper containing catalysts. The first catalyst was used in nitrobenzene hydrogenation to aniline and the second was used in a low temperature water-gas shift reaction. Experimental results show that application of these two methods leads to similar results. Experimental data obtained allow for monitoring changes in the texture of the catalyst grains and intraparticle diffusivity of gaseous reagents at different states of the catalyst activity and use, which can be used as criteria for designing optimal industrial catalyst pellets.

Graphical abstractThe preparation of catalyst pellets with small pore tortuosity is one of the objectives in selecting pelletizing technology and pelletizing conditions. The intra-particle mass transfer parameters are helpful tool for achieving this aim.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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