Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
59296 | Chinese Journal of Catalysis | 2010 | 4 Pages |
Abstract
A new catalytic procedure for the chemoselective oxidation of sulfides to sulfoxides was studied. A variety of aliphatic and aromatic sulfides were subjected to sulfoxidation by combining poly(4-vinyl pyridinium nitrate), silica sulfuric acid (SiO2-OSO3H), and catalytic amounts of ammonium bromide in CH2Cl2 in the presence of a few drops of water at room temperature. Excellent yields were obtained.
Graphical abstractVarious sulfides were oxidized chemoselectively to their corresponding sulfoxides by poly(4-vinylpyridinium nitrate), silica sulfuric acid, and a catalytic amount of ammonium bromide at room temperature under mild and heterogeneous conditions.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Arash GHORBANI-CHOGHAMARANI, Sara SARDARI,