Selective Catalytic Dehydration of 1,4-Butanediol to 3-Buten-1-ol over CeO2 with Different Morphology

CeO2 catalyst samples were prepared by the precipitation method using Ce(NO3)3·6H2O as a precursor. These samples were characterized by N2 adsorption-desorption, X-ray diffraction, high resolution transmission electron microscopy, and H2 temperature-programmed reduction. The catalytic performance of these samples for the selective dehydration of 1,4-butanediol to 3-buten-1-ol was investigated. The results show that the CeO2 catalysts that were prepared using different precipitants exhibited different morphology. The CeO2sample precipitated by sodium carbonate showed regular rectangular morphology with clear edges, larger crystallite size, well-grown crystals and preferentially exposed (111) facets. It also had higher activity and higher selectivity in the selective dehydration of 1,4-butanediol to 3-buten-1-ol with yield as high as 59.7%.