| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 59610 | Chinese Journal of Catalysis | 2007 | 4 Pages |
Abstract
PdCl2/polystyrene-supported phenol (PS-phenol) was presented as a cocatalyst for the acetalization of methyl acrylate with methanol in supercritical carbon dioxide under oxygen atmosphere. After methyl acrylate was completely converted, the highest yield and selectivity for methyl 3,3-dimethoxypropanoate were 97.7% and 100%, respectively. Compared with small molecular acidic co-catalysts, the separation of PS-phenol from the reaction system by simple filtration made the recycling of precious palladium practical and convenient.
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