| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 601162 | Colloids and Surfaces B: Biointerfaces | 2011 | 8 Pages |
Biosorption characteristics of Ananas comosus (pineapple) leaf powder was investigated for decolorization of Basic Green 4 (BG 4), a cationic dye from its aqueous solutions employing a batch experimental set-up. Parameters that influence the sorption process such as pH, biosorbent dosage, contact time, initial dye concentration and temperature were systematically studied. The optimum conditions for removal of BG 4 were found to be pH 9.0, contact time = 150 min, biosorbent dosage = 5.0 g L−1, initial dye concentration = 50 mg L−1. The temperature had a strong influence on the biosorption process. Further, the biosorbent was characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and Brunauer, Emmett, Teller (BET) surface area and pore size analysis. Experimental biosorption data were modeled by Langmuir, Freundlich and Dubinin–Radushkevich (D–R) isotherms. The biosorption process followed the Langmuir isotherm model with high coefficients of correlation (R2 > 0.99) at different temperatures. The pseudo second order kinetic model fitted well in correlation to the experimental results. Activation energy of the biosorption process (Ea) was found to be 45.79 kJ mol−1 by using the Arrhenius equation, indicating chemisorption nature of BG 4 sorption onto pineapple leaf powder. Thermodynamic parameters suggest that the biosorption process is spontaneous and exothermic in nature. Overall, the present findings suggest that this environmentally friendly, efficient and low-cost biosorbent may be useful for the removal of BG 4 from aqueous media.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Biosorption behaviour of pineapple leaf powder (PLP) for Basic Green 4 was investigated. ► Different operating parameters were optimized to evaluate biosorption performance of PLP. ► The kinetic data of dye biosorption fitted well to the pseudo-second order model. ► The biosorption process followed Langmuir isotherm model. ► Thermodynamic study indicated that the dye biosorption process was exothermic.
