| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 60418 | Chinese Journal of Catalysis | 2008 | 5 Pages |
Abstract
A Pd(OAc)2/[mmim]I ([mmim]I=1-methyl-3-methylimidazolium iodide) catalyst system was applied to the oxidative carbonylation of aliphatic amines, aromatic amines, and amino alcohols to carbamates, ureas, and 2-oxazolidinones under different conditions. The catalytic turnover frequencies (TOF, moles of amines converted per mole of catalyst per hour) were 12417, 17368, and 4114 h−1 for the production of methyl N-phenyl carbamate, N,N′-diphenyl urea, and 2-benzoxazolinone, respectively.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
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