| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 60634 | Journal of Catalysis | 2016 | 5 Pages |
Abstract
•A rare example of a hetero-bimetallic Pd–Ru anionic dicarbene complex is presented.•The compound is used in homogeneous tandem catalysis.•The catalytic selectivity depends on the timely order of solvent addition.
A hetero-bimetallic Pd–Ru N-Heterocyclic Dicarbene (NHDC) complex was synthesized from a Ag–Ru complex by transmetalation. The Pd–Ru system displays high catalytic activity in tandem Suzuki–Miyaura cross-coupling/transfer hydrogenation reaction of bromoaryl ketones with boronic acids in toluene and 2-propanol in the presence of KOH.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Mario J. Bitzer, Fritz E. Kühn, Walter Baratta,