Pulsed laser deposition of bimetallic gold–platinum nanoparticles on cerium oxide and their characterisation by X-ray photoelectron spectroscopy and temperature-programmed desorption of isotopically labelled carbon monoxide

Bimetallic Au–Pt nanoparticles on cerium oxide supports were prepared using pulsed laser deposition (PLD) at room temperature and investigated using X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD) of isotopically labelled carbon monoxide 13C18O. The metal deposition caused a partial reduction of Ce4+ to Ce3+. Two components in the spectra of Au (4f) and Pt (4f) photoelectrons were observed and assigned to the charged and metallic state of metals in the nanodeposits. The abundance of the charged species decreased with an increasing amount of the deposited metals and with thermal treatment of the samples. The adsorption properties of the prepared nanodeposits were examined using repeated adsorption–desorption runs of the labelled 13C18O molecules. Carbon monoxide desorbed as 13C18O with a maximum at temperatures ranging from 420 K to 500 K and as 13C16O containing 16O oxygen exchanged from the supporting oxide at temperatures from 480 to 580 K. The TPD curves from bimetallic Au–Pt nanoparticles differed from those obtained from Pt monometallic deposits by (1) a lower temperature of maximum (Tmax) of the 13C16O desorption peak in the first desorption run and a higher Tmax of 13C18O for the second desorption, (2) a substantial decrease in the adsorption capacity after repeated adsorption–desorption cycles and (3) stable 13C16O/13C18O desorption peak area ratios during repeated adsorption–desorption cycles. Oxidation of CO to CO2 was observed on all metal deposits on CeO2−x and also to a lower extent on bare CeO2−x surfaces. In contrast to the CO desorption, the desorption curves of CO2 from Pt/CeO2−x were similar to those from bimetallic Au–Pt nanodeposits.

Graphical abstractBimetallic Au–Pt nanoparticles on CeO2−x supports were prepared using pulsed laser deposition. Two components in the spectra of Pt (4f) and Au (4f) photoelectrons were observed, which corresponded to the charged and metallic states of both metals in the deposits. TPD of isotopically labelled 13C18O confirmed presence of bimetallic phase.Figure optionsDownload full-size imageDownload high-quality image (82 K)Download as PowerPoint slideHighlights► Au–Pt/CeO2−x model catalyst prepared by pulsed laser deposition. ► Deposition of Au–Pt on CeO2−x caused partial reduction of Ce4+ to Ce3+. ► Charged and metallic states of both metals in the Au–Pt deposits were present. ► TPD of isotopically labelled 13C18O confirmed presence of bimetallic phase. ► The cationic states of both metals participate in the oxidation of carbon monoxide.