| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 61723 | Journal of Catalysis | 2011 | 9 Pages |
The kinetics of the catalytic hydrodeoxygenation of phenol and substituted phenols has systematically been investigated on the dual-functional catalyst system Pd/C and H3PO4 in order to better understand the elementary steps of the overall reaction. The reaction proceeds via stepwise hydrogenation of the aromatic ring, transformation of the cyclic enol to the corresponding ketone, hydrogenation of the cycloalkanone to the cycloalkanol and its subsequent dehydration as well as the hydrogenation of the formed cycloalkene. The presence of dual catalytic functions is indispensible for the overall hydrodeoxygenation. The dehydration reaction is significantly slower than the hydrogenation reaction and the keto/enol transformation, requiring a significantly larger concentration of Brønsted acid sites compared to the available metal sites for hydrogenation.
Graphical abstractHydrodeoxygenation of phenol and substituted phenols over dual-functional Pd/C and H3PO4 catalysts proceeds via stepwise hydrogenation of the aromatic ring, transformation of the cyclic enol to the corresponding ketone, hydrogenation of the cycloalkanone to the cycloalkanol and its subsequent dehydration as well as the hydrogenation of the formed cycloalkene.Figure optionsDownload full-size imageDownload high-quality image (26 K)Download as PowerPoint slideResearch highlights► Dual-functional catalysts hydrodeoxygenate substituted phenols in water. ► Suitable reaction conditions lead to cycloalkane phase. ► Acid function is required to break the C–O bond via hydrolysis or dehydration.
