Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NOx with NH3

Superior activity and selectivity of a Cu ion-exchanged SSZ-13 zeolite in the selective catalytic reduction (SCR) of NOx with NH3 were observed, in comparison with Cu-beta and Cu-ZSM-5 zeolites. Cu-SSZ-13 was not only more active in the NOx SCR reaction over the entire temperature range studied (up to 550 °C), but also more selective toward nitrogen formation, resulting in significantly lower amounts of NOx by-products (i.e., NO2 and N2O) than the other two zeolites. In addition, Cu-SSZ-13 demonstrated the highest activity and N2 formation selectivity in the oxidation of NH3. The results of this study strongly suggest that Cu-SSZ-13 is a promising candidate as a catalyst for NOx SCR with great potential in after-treatment systems for either mobile or stationary sources.

Graphical abstractNOx conversion profiles for NH3 SCR on Cu-SSZ-13 (squares), Cu-beta (circles) and Cu-ZSM-5 (triangles).Figure optionsDownload full-size imageDownload high-quality image (85 K)Download as PowerPoint slide