Aromatization of hexane over Pt/KL catalyst: Role of intracrystalline diffusion on catalyst performance using isotope labeling

Aromatization of hexane using an equimolar mixture of C6H14 and C6D14 was investigated over 1%Pt/KL at 500 °C and 1 atm. There is hardly any kinetic isotope effect indicating that entry of hexane molecules into the wider lobes of the channels of L-zeolite through the narrow apertures leads to single-file hexane access to Pt0 sites. The catalyst displayed high activity and selectivity to benzene and excellent stability at the tested conditions during hexane dehydrocyclization. It is proposed that controlling the entry of hexane into the lobes of the L-zeolite containing the active sites is the reason for the exceptional Pt/KL catalytic performance for aromatization because the narrow windows of the L-zeolite channels inhibit the occurrence of bimolecular reactions that lead to coke formation and catalyst deactivation.

Graphical abstractThe kinetic isotope effect (kH/kD) over 1%Pt/KL was determined at 500 °C and 1 atm using an equimolar mixture of C6H14 and C6D14. Results indicate that the excellent catalytic performance of Pt/KL for hexane aromatization may be explained by the unique structure of L-zeolite. The narrow windows of the uni-axial channels control hexane entry into the wider lobes where the Pt sites reside, restricting the access of hexane to Pt to a single-file basis.Figure optionsDownload full-size imageDownload high-quality image (40 K)Download as PowerPoint slide