Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
62785 | Journal of Catalysis | 2007 | 5 Pages |
Abstract
An amphiphilic proline-based organocatalyst was assembled on the interface of water and oil, resulting in a W/O emulsion. The chiral catalyst in emulsion significantly enhances the reactivity and stereoselectivity of the direct asymmetric aldol reactions, which can be attributed mainly to the larger interfacial surface area and uniformly distributed catalyst molecules in the interface of the emulsion droplets.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Lin Zhong, Qiang Gao, Jinbo Gao, Jianliang Xiao, Can Li,