Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
63045 | Journal of Catalysis | 2008 | 4 Pages |
Abstract
We compared the efficacies of urea + hydrogen peroxide (U+HP) and hydrogen peroxide (HP) as an oxidizing agent in the epoxidation of propylene catalyzed by a titanium silicate-1 (TS-1) molecular sieve. The TS-1 catalyst exhibited good performance and stability in the TS-1/(U+HP) system. EPR results showed that more active Ti-superoxo species led to better performance of TS-1 in the TS-1/(U+HP) system than in the TS-1/HP system.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Weiguo Cheng, Xiangsheng Wang, Gang Li, Xinwen Guo, Suojiang Zhang,