Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6306125 | Chemosphere | 2016 | 6 Pages |
Abstract
In order to elucidate the metal-alcohol hydrodechlorination reaction mechanism, several experiments using chloroanisoles as substrates were performed. Thus, chloroanisoles were stirred at 60 °C for 2 h with a mixture of Ca, methanol and various reduction catalysts. The use of deuterated methanol and zeta potential experiments offered supplementary informations, pointing toward a probable radicalic mechanism that occurs on Ca and Pd/C surfaces.
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Authors
Yoshiharu Mitoma, Yumi Katayama, Alina M. Simion, Hiroyuki Harada, Mitsunori Kakeda, Naoyoshi Egashira, Cristian Simion,