Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6307232 | Chemosphere | 2016 | 7 Pages |
Abstract
Atomic absorption spectrometry and inductively coupled plasma-mass spectrometry are widely used for determination of heavy metals due to their low detection limits. However, they are not applicable to on-site measurements of heavy metals as bulky equipment, and highly skilled laboratory staffs are needed as well. In this study, a novel analytical method using a rotary disc voltammetric (RDV) sensor has been successfully designed, fabricated and characterized for semi-continuous and on-site measurements of trace levels of Pb(II) in non-deoxygenating solutions. The square wave anodic stripping voltammetry was used to improve the sensitivity of the Pb(II) detection level with less than 10 nM (2 μg Lâ1). The RDV sensor has 24-sensing holes to measure concentrations of Pb(II) semi-continuously at sampling sites. Each sensing hole consists of a silver working electrode, an integrated silver counter, and a quasi-reference electrode, which requires only a small amount of samples (<30 μL) for measurement of Pb(II) without disturbing and/or clogging the sensing environment. In addition, the RDV sensor showed a correlation coefficient of 0.998 for the Pb(II) concentration range of 10 nM-10 μM at the deposition time of 180 s and its low detection limit was 6.19 nM (1.3 μg Lâ1). These results indicated that the advanced monitoring technique using a RDV sensor might provide environmental engineers with a reliable way for semi-continuous and on-site measurements of Pb(II).
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Authors
Yong-Gu Lee, Jungyoup Han, Soondong Kwon, Seoktae Kang, Am Jang,