| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 6311097 | Chemosphere | 2013 | 9 Pages |
Abstract
⺠The bacterial dehalogenase LinB converts HBCDs like HCHs. ⺠Mono- and dihydroxylated products are formed during HBCD biotransformations. ⺠XRD-analysis revealed the solid-state structures of δ-HBCD and α2-PBCDOH. ⺠From these structures, the stereochemistry of the LinB-catalyzed transformation was elucidated. ⺠LinB induced a regio- and stereoselective, SN2-type substitution reaction.
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Authors
Norbert V. Heeb, Daniel Zindel, Heidi Graf, Valeria Azara, W. Bernd Schweizer, Birgit Geueke, Hans-Peter E. Kohler, Peter Lienemann,