Article ID Journal Published Year Pages File Type
6335294 Applied Geochemistry 2013 8 Pages PDF
Abstract

•High V/Ca in corals from the Gulf of Thailand suggested oil pollution since the 1990s.•Decreased Cd/Ca in the corals since 1985 indicated deceasing Cd input in the Gulf.•Pb/Ca in the corals reflected the use history of leaded gasoline in Thailand since 1983.

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been used to assess the impact of metal pollution on Porites skeletons taken from the Gulf of Thailand since the 1980s. The collection period coincided with a series of laws enacted by the Thai government to curb environmental pollution. The extent of metal pollution by riverine input, including aerosol deposits, was assessed by comparing the metal/Ca (Me/Ca) ratios in the Thai corals to the ratios of another colony of corals sampled from Rukan-sho, a relatively unpolluted coral reef located in Okinawa, Japan. In this comparison, high riverine inputs of Ba, V, Cd and Pb were observed in the Thai coral samples. Higher V/Ca ratios found in the Thai corals compared to the Rukan-sho coral suggest anthropogenic V inputs due to fuel oil pollution in the Gulf since the late 1990s. The levels of Cd in the coral suggest a gradual decrease in the Gulf in the late 1990s, with a drastic drop in concentration from the 1980s. The historical variation in Pb/Ca ratios recorded in the coral skeletons suggests that exposure to anthropogenic Pb was a result of discharge from urbanized areas from 1984 to 1998, which has been gradually reduced since Thailand prohibited the use of leaded gasoline in the late 1990s.

Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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