Comparison of the mixing state of long-range transported Asian and African mineral dust

Mineral dust from arid regions represents the second largest global source of aerosols to the atmosphere. Dust strongly impacts the radiative balance of the earth's atmosphere by directly scattering solar radiation and acting as nuclei for the formation of liquid droplets and ice nuclei within clouds. The climate effects of mineral dust aerosols are poorly understood, however, due to their complex chemical and physical properties, which continuously evolve during atmospheric transport. This work focuses on characterizing atmospheric mineral dust from the two largest global dust sources: the Sahara Desert in Africa and the Gobi and Taklamakan Deserts in Asia. Measurements of individual aerosol particle size and chemical mixing state were made at El Yunque National Forest, Puerto Rico, downwind of the Sahara Desert, and Gosan, South Korea, downwind of the Gobi and Taklamakan Deserts. In general, the chemical characterization of the individual dust particles detected at these two sites reflected the dominant mineralogy of the source regions; aluminosilicate-rich dust was more common at El Yunque (∼91% of El Yunque dust particles vs. ∼69% of Gosan dust particles) and calcium-rich dust was more common at Gosan (∼22% of Gosan dust particles vs. ∼2% of El Yunque dust particles). Furthermore, dust particles from Africa and Asia were subjected to different transport conditions and atmospheric processing; African dust showed evidence of cloud processing, while Asian dust was modified via heterogeneous chemistry and direct condensation of secondary species. A larger fraction of dust detected at El Yunque contained the cloud-processing marker oxalate ion compared to dust detected at Gosan (∼20% vs ∼9%). Additionally, nearly 100% of dust detected at Gosan contained nitrate, showing it was aged via heterogeneous reactions with nitric acid, compared to only ∼60% of African dust. Information on the distinct differences in the chemical composition of mineral dust particles, as well as the mechanisms and extent of atmospheric processing, is critical for assessing its impacts on the earth's radiative budget through scattering, absorption, and nucleating cloud droplets and ice crystals.