Article ID Journal Published Year Pages File Type
6342264 Atmospheric Environment 2012 8 Pages PDF
Abstract
► First kinetic study of OH and Cl-initiated oxidation of two unsaturated nitriles. ► Experiments in large volume photoreactors using “in situ” FTIR. ► Experimental rate constants were compared by SAR method. ► Free energy relationships were used to estimate rate constants. ► Atmospheric lifetimes of nitriles were discussed.
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Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Atmospheric Science
Preview
Gas-phase reactivity study of (E)-3-pentenenitrile and 4-pentenenitrile towards OH radicals and Cl atoms at atmospheric pressure
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