Article ID Journal Published Year Pages File Type
635388 Journal of Membrane Science 2011 9 Pages PDF
Abstract
► Tracer diffusion coefficients in a multicomponent solvent-solvent-polymer system were successfully estimated by PFG-NMR measurements on a free-standing crosslinked PDMS. ► Experimental diffusivities were correlated with available diffusion models (i.e., Vrentas & Duda diffusion theory and Wesselingh & Bollen multicomponent diffusion model). Therefore, a method was developed to calculate free volume parameters of the compounds/system. ► A discussion about advantages, disadvantages, theoretical limitations, necessary assumptions, as well as a way to proceed in modeling of nanofiltration has been done.
Related Topics
Physical Sciences and Engineering Chemical Engineering Filtration and Separation
Authors
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