Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
635388 | Journal of Membrane Science | 2011 | 9 Pages |
Abstract
⺠Tracer diffusion coefficients in a multicomponent solvent-solvent-polymer system were successfully estimated by PFG-NMR measurements on a free-standing crosslinked PDMS. ⺠Experimental diffusivities were correlated with available diffusion models (i.e., Vrentas & Duda diffusion theory and Wesselingh & Bollen multicomponent diffusion model). Therefore, a method was developed to calculate free volume parameters of the compounds/system. ⺠A discussion about advantages, disadvantages, theoretical limitations, necessary assumptions, as well as a way to proceed in modeling of nanofiltration has been done.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Daniel Fierro, Nico Scharnagl, Thomas Emmler, Adriana Boschetti-de-Fierro, Volker Abetz,