Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6353966 | Waste Management | 2015 | 7 Pages |
Abstract
In order to suggest a limit value for gypsum (CaSO4) for the suppression of hydrogen sulfide (H2S) generation at an inert solid waste landfill site, the relationship between raw material (SO4 and organic matter) for H2S generation and generated H2S concentration, and the balance of raw material (SO4) and product (H2S) considering generation and outflow were investigated. SO4 concentration should be less than approximately 100Â mg-SO4/L in order to suppress H2S generation to below 2000Â ppm. Total organic carbon (TOC) concentration should be less than approximately 200Â mg-C/L assuming a high SO4 concentration. The limit value for SO4 in the ground is 60Â mg-SO4/kg with 0.011Â wt% as gypsum dihydrate, i.e., approximately 1/10 of the limit value in inert waste as defined by the EU Council Decision (560Â mg-SO4/kg-waste). The limit value for SO4 in inert waste as defined by the EU Council Decision is high and TOC is strictly excluded. The cumulative amount of SO4 outflow through the liquid phase is much larger than that through the gas phase. SO4 concentration in pore water decreases with time, reaching half the initial concentration around day 100. SO4 reduction by rainfall can be expected in the long term.
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Geotechnical Engineering and Engineering Geology
Authors
Hiroshi Asakura,