Metal pollution status in Zhelin Bay surface sediments inferred from a sequential extraction technique, South China Sea

Surface sediments collected from Zhelin Bay, the largest mariculture base of eastern Guangdong Province, were analyzed for total metal concentrations and chemical speciation. The results demonstrated that the average total concentration (mg/kg) ranges were 36.7-65.8 (Pb), 53.8-98.8 (Cr), 39.0-87.1 (Ni), 50.9-144.5 (Cu), and 175.0-251.2 (Zn), which were clearly higher with respect to their corresponding benchmark values. The predominant speciation of Pb was reducible and comprised a residual fraction, whereas a major portion (57.6-95.4%) of Cr, Ni, Cu, and Zn was strongly associated with the residual fractions. Taking as a whole, surface sediments of Zhelin Bay had a 21% probability of toxicity based on the mean effects range-median quotient.