Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
636205 | Journal of Membrane Science | 2010 | 11 Pages |
Abstract
A novel dual-layer nanofiltration (NF) hollow fiber membrane was fabricated by the simultaneous co-extrusion of Torlon® polyamide-imide and cellulose acetate dopes through a triple-orifice spinneret in a dry-jet wet phase inversion process. For the first time, the nanopores of dual-layer hollow fiber membranes were molecularly designed by controlling the phase inversion process with the aid of various non-solvent additives into the polymer solutions. Compared to ethanol and 2-propanol, the addition of methanol into the dope led to a significantly decreased pore size but dramatically increased pure water permeability. The improved NF performance may be attributed to (1) a controllable thin selective outer layer; (2) a less resistant interface between the outer and inner layers; and (3) a fully porous substructure with reduced transport resistance. In addition to non-solvent additives, spinneret temperature also plays an important role in designing dual-layer hollow fiber membranes with desirable NF performance. When the spinneret temperature was increased from 25 °C to 50 °C, the mean effective pore radius and the pure water permeability were simultaneously decreased, which was due to the formation of a denser surface skin and a more compact interface between the two layers. In addition to exhibiting a higher rejection of divalent anions than monovalent anions, and a lower rejection of divalent cations at pH 7.0, the newly developed NF dual-layer hollow fiber membranes with methanol as additive has a relatively high pure water permeability of 11.93 l mâ2 barâ1 hâ1 with a mean effective pore radius of 0.63 nm. These concepts hold great potential for the design of tailor-made NF membranes for various industrial applications.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Shi Peng Sun, Kai Yu Wang, Na Peng, T. Alan Hatton, Tai-Shung Chung,