Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
6362565 | Marine Pollution Bulletin | 2010 | 9 Pages |
Abstract
Hudson River sediment microcosms from Piles Creek (PC), Piermont Marsh (PM), and Iona Island (II) were amended with â¼100 mM nitrate or sulfate to stimulate anaerobic bioremediation. Nitrate and sulfate decreased over two years of field incubation and the fraction of these losses due to diffusion to the water column was predicted using Fick's law. Apparent diffusion (Dapp) values of 1-4 Ã 10â10 m2 sâ1 predicted the majority of loss/gain from/to the sediments by 700 d, but not at all times. Effective diffusion (Deff) values predicted by the porosity function (Deff = Dmol ε4/3) were larger than those observed in the field, and field data indicates a cube power relationship: Deff = Dmol ε3. Dapp greatly increased in surficial layers at PM and PC in year two, suggesting that bioadvection caused by bioturbating organisms had occurred. The effects of bioturbation on transport to/from the sediments are modeled, and results can be applied to various sediment treatment scenarios such as capping.
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Oceanography
Authors
Menka Mittal, Karl J. Rockne,