Polyamide-imide/polyetherimide dual-layer hollow fiber membranes for pervaporation dehydration of C1–C4 alcohols

To circumvent the common swelling and deteriorated performance of integral asymmetric hollow fiber membranes for pervaporation dehydration, we have developed novel polyamide-imide (PAI)/polyetherimide (PEI) hollow fiber membranes with synergized performance with the aid of dual-layer spinning technology. Dehydration of C1–C4 alcohols has been conducted and the orders of their fluxes and permeances have been analyzed. The hollow fibers spun at 2 cm air gap and annealed at 75 °C exhibit the highest pervaporation performance: separation factors for t-butanol/water and iso-butanol/water binary systems are greater than 50,000 with flux more than 700 g/m2 h. A comparison with literature data shows that the newly developed membranes outperform most other polymeric membranes for the dehydration of IPA and butanols. The dual-layer hollow fiber membranes also exhibit good long-term stability up to 200 h. The superior performance can be attributed to (1) the balanced properties of PAI as the selective layer for dehydration pervaporation; (2) the low water uptake and less swelling characteristic of the PEI supporting layer; and (3) the desirable membrane morphology consisting of a fully porous inner layer, a porous interface, and an ultrathin dense-selective outer skin.