Article ID Journal Published Year Pages File Type
637417 Journal of Membrane Science 2009 10 Pages PDF
Abstract
The long-term stability of Pd-23%Ag/stainless steel composite membranes has been examined in H2/N2 mixtures as a function of both temperature and feed pressure. During continuous operation, the membrane shows a good stability at 400 °C while the N2 leakage increases very slowly at a temperature of 450 °C (Pfeed = 10 bar). After 100 days of operation (Pfeed = 5-20 bar, T = 350-450 °C), the N2 permeance equals 7.0 × 10−9 mol m−2 s−1 Pa−1, which indicates that the H2/N2 permselectivity still lies around 500, based on a H2 permeance equal to 3.0 × 10−6 mol m−2 s−1 Pa−1. Despite the generation of small pinholes, a membrane life-time of several (2-3) years (T ≤ 425 °C) is estimated for the experimental conditions employed based on long-term stability tests over 100 days. Post-process characterisation shows a considerable grain growth and micro-strain relaxation in the Pd-23%Ag membrane after the prolonged permeation experiment. Changes in surface area are relatively small. In addition, segregation of Ag to the membrane surfaces is observed. The formation of pinholes is identified as the main source for the increased N2 leakage during testing at higher temperature.
Related Topics
Physical Sciences and Engineering Chemical Engineering Filtration and Separation
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