Improved catalytic performance of Ni catalysts for steam methane reforming in a micro-channel reactor

Milliseconds process to produce hydrogen by steam methane reforming (SMR) reaction, based on Ni catalyst rather than noble catalyst such as Pd, Rh or Ru, in micro-channel reactors has been paid more and more attentions in recent years. This work aimed to further improve the catalytic performance of nickel-based catalyst by the introduction of additives, i.e., MgO and FeO, prepared by impregnation method on the micro-channels made of metal-ceramic complex substrate. The prepared catalysts were tested in the same micro-channel reactor by switching the catalyst plates. The results showed that among the tested catalysts Ni-Mg catalyst had the highest activity, especially under harsh conditions, i.e., at high space velocity and/or low reaction temperature. Moreover, the catalyst activity and selectivity were stable during the 12 h on stream test even when the ratio of steam to carbon (S/C) was as low as 1.0. The addition of MgO promoted the active Ni species to have a good dispersion on the substrate, leading to a better catalytic performance for SMR reaction.

Graphical AbstractSMR catalytic performance of nickel-based catalyst in micro-channel reactor has been improved by the introduction of extra additives. MgO favors the increase of methane conversion and Ni-Fe alloy favors the increase of CO2 selectivity.Figure optionsDownload full-size imageDownload as PowerPoint slide