Article ID Journal Published Year Pages File Type
6436765 Chemical Geology 2013 16 Pages PDF
Abstract

•We investigated sedimentary carbonates from the Kolosjoki Sedimentary Formation.•The Kolosjoki formation postdates the Lomagundi-Jatuli isotope excursion.•We found a δ13C trend from − 2 to 3‰ in the Kolosjoki succession.•The results provide evidence for a minimum in the δ13C curve at 2060-1970 Ma.

The Kolosjoki Sedimentary Formation of the Pechenga Greenstone Belt, north eastern Fennoscandia, records the aftermath of the Paleoproterozoic global positive δ13C excursion in sedimentary carbonates (the Lomagundi-Jatuli isotope excursion). The goals of this research were to provide detailed new data on the δ13C trend in the Kolosjoki Sedimentary Formation and generate a secular δ13C curve for the time period immediately succeeding the Lomagundi-Jatuli isotope excursion. For these purposes, sedimentary carbonate samples from two new drillcores representing the Kolosjoki Sedimentary Formation were collected. In total 88 whole-rock samples and 67 micro-drilled subsamples (ca. 1-3 mg) were analyzed for the isotope composition of C and O, the whole-rock elemental abundances, and for the composition of the acid-soluble fraction. The Kolosjoki carbonate rocks are dolostone or calcitic dolostone (Mg/Ca = 0.50-0.67) with minor limestone (Mg/Ca = 0.04-0.06). Only weak correlation was observed between the Mn/Sr ratios and the δ13C and δ18O values, and the carbonate samples have likely retained their near-primary δ13C values. The sedimentary carbonate rocks show first low δ13C values at − 2 to − 1‰ and then a subtle, upward increasing δ13C trend from ca. 1 to 3‰. The increasing δ13C trend is interpreted to record a recovery from a δ13C minimum following the Lomagundi-Jatuli isotope excursion.

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Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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