Article ID Journal Published Year Pages File Type
6438200 Geochimica et Cosmochimica Acta 2014 17 Pages PDF
Abstract
The 13C NMR spectra show that carbonate (CO32−) environments can be attributed to carbonate species associated to non-bridging oxygen in agreement with the depolymerized nature of the investigated compositions. Two singular additional carbonated species were also identified with 13C NMR signatures at 161 and 165 ppm. Those species are assigned to isolated K+…CO32−…H+ and Na+…CO32−…H+ carbonate species. The presence of such isolated carbonate species is interpreted as possible precursors to carbonatitic melt genesis.
Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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