Article ID Journal Published Year Pages File Type
6438738 Geochimica et Cosmochimica Acta 2014 31 Pages PDF
Abstract
MELTS (Ghiorso and Sack, 1995; Asimow and Ghiorso, 1998) models of one VLT, one low-Ti and two high-Ti mare basalts and one KREEP basalt all show evolution from low to high Fe# residual liquids during fractional crystallization; however strong enrichments in FeO-concentrations are limited to the VLT and low-Ti liquids. In the high-Ti liquids, crystallization of Fe-Ti-oxides prevents enrichment in FeO, and the increases in Fe# are due to depletion of MgO. Fe-Ti-oxide fractionation results in steady silica-enrichment in the high-Ti mare compositions. Intervals of FeO-enrichment on the VLT and low-Ti mare liquid lines of descent are linked to shifts from olivine to pyroxene crystallization. The onset of plagioclase feldspar crystallization limits the depletion of FeO during crystallization of one high-Ti mare basalt and of the KREEP basalt composition modeled.
Related Topics
Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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